The 31-year-old Black Swan star is the epitome of demure chic in the gorgeous shoot and is seen softly gazing at the camera while wearing a white knitted jumper.
In another shot, the actress is pictured looking especially casual in a simple dark grey top and artfully worn in jeans.
Demure: Natalie Portman is pictured during her latest photoshoot for Dior Perfumes
Natural beauty: The actress gazes into the camera while covering up in a knitted jumper
The shoot is a stark contrast to her most recent advert for the Diorskin Nude range, where the brunette beauty is pictured lying topless over a chaise lounge.
Natalie also stripped off for her previous advert for Miss Dior Cherie perfume, where she soaks in a tub wearing nothing but her Dior sunglasses.
Pretty in pink: The jeans and jumper are nowhere
to be seen as Natalie changes in to an elegant sugary pink dress and
perches on a chaise
The Oscar-winning actress wears the brand's new 'nude' range which promises a more natural look
'My grandmother believes you don't leave the house unless you have perfect hair and make-up, so she is always at me for not brushing my hair or not putting on enough make-up,' she said.
'I love Sofia Coppola's whole aesthetic. She presents herself in a ladylike fashion and has so much personality,' the mother of one-year old boy Aleph added.
That said, Natalie did admit that she never leaves the house without a lipstick: 'I keep three lipsticks with me, always, one nude, everyday colour, plus a red and a plum for dressing up.'
Taking the plunge: Natalie's previous ad for Miss Dior Cherie perfume
Iconic: The 20 second ad is set to the classic Serge Gainsbourg tune 'Je t'aime...Moi non plus
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